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I wouldn’t recommend installing a distro just to install a different DE. IMHO, you should be fine with cinnamon. I’m using Linux Mint 21.3 with cinnamon on an x201 (Thinkpad released in 2010), though I did up the RAM to the 8GB max. However, if you want XFCE, is there a reason you don’t want to use Linux Mint 21.3 with XFCE? If that’s no good for you, I’d recommend finding a distro that fits most of your needs right out of the box, maybe Peppermint Linux or MX Linux?
Have you put an SSD in there, or are you still running on spinning rust? In my experience, even a cheap SSD will make a huge difference.